4.7 Article

Tunability of Band Gaps in Metal-Organic Frameworks

Journal

INORGANIC CHEMISTRY
Volume 51, Issue 16, Pages 9039-9044

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic301189m

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Funding

  1. Office of Science, U.S. Department of Energy [DE-AC02-06CH11357]
  2. Argonne National Laboratory
  3. USF
  4. NIU-Argonne NanoScience via InSET
  5. NSF [CBET-1150617]
  6. Div Of Chem, Bioeng, Env, & Transp Sys
  7. Directorate For Engineering [1150617] Funding Source: National Science Foundation

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The tunability of the band gaps in Zn-based metal-organic frameworks (MOFs) has been experimentally demonstrated via two different approaches: changing the cluster size of the secondary building unit (SBU) or alternating the conjugation of the organic linker.

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