4.7 Article

Biomimetic Catalysis of a Porous Iron-Based Metal-Metalloporphyrin Framework

Journal

INORGANIC CHEMISTRY
Volume 51, Issue 23, Pages 12600-12602

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic301923x

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Funding

  1. University of South Florida

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A porous metal-metalloporphyrin framework, MMPF-6, based upon an iron(III)-metalated porphyrin ligand and a secondary binding unit of a zirconium oxide cluster was constructed; MMPF-6 demonstrated interesting peroxidase activity comparable to that of the heme protein myoglobin as well as exhibited solvent adaptability of retaining the peroxidase activity in an organic solvent.

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