Journal
INORGANIC CHEMISTRY
Volume 51, Issue 7, Pages 3947-3949Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic3002724
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- Australian Research Council
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Three isostructural hexanuclear lanthanide(III) clusters are reported (Ln(III) = Gd, Tb, and Dy). The metallic core of each complex displays an unusual arrangement of ions, which is stabilized by a mu(6)-carbonate ligand. Magnetic studies show that the Ln(III) ions in each compound are weakly exchange coupled, with the Tb and Dy analogues displaying single-molecule-magnet behavior.
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