4.7 Article

Microporous Zinc Tris[(4-carboxyl)phenylduryl]amine Framework with an Unusual Topological Net for Gas Storage and Separation

Journal

INORGANIC CHEMISTRY
Volume 51, Issue 4, Pages 1995-1997

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic202713e

Keywords

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Funding

  1. National Basic Research Program of China (973 Programs) [2011CB932504, 2012CB821705]
  2. NSFC [21073191, 21103189]
  3. NSF of Fujian Province [2011J06005, 2010J05039]
  4. CAS [KJCX2-YW-H21]

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By employment of a new tris[(4-carboxyl)phenylduryl]amine ligand to assembly with the Zn2+ ion, a new topological net built from four coordinatively linked ths nets is first evidenced in the 2-fold-interpenetrating framework FIR-1, which shows potential applications in gas storage and separation.

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