Journal
INORGANIC CHEMISTRY
Volume 51, Issue 7, Pages 4398-4402Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic3002543
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Funding
- Finnish Centre of Excellence in Computational Molecular Science
- Faculty of Science of the University of Helsinki [7500101]
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We report on the preparation and characterization of three new noble-gas molecules ClXeCN, ClXeNC, and BrXeCN. These molecules are synthesized by 193 nm photolysis and thermal annealing of ClCN and BrCN in a xenon matrix. The absorption spectra are measured in the mid- and far-infrared regions, and the assignment is supported by isotope substitution and quantum chemical calculations at the B3LYP and MP2 levels of theory. The present results demonstrate a way to prepare other noble-gas molecules of this type.
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