Journal
INORGANIC CHEMISTRY
Volume 51, Issue 6, Pages 3343-3345Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic2016676
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Funding
- DST, New Delhi, India [SR/FTP/CS-44/2006]
- CSIR, MHRD
- UGC India
- NIH [1R15 ES019129-01]
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The copper complex [Cu((t)BuPhimp)(Cl)] (1) derived from tridentate ligand (t)BuPhimpH having N2O donors was synthesized, and its molecular structure was determined. A phenoxyl radical complex was generated in solution at room temperature using Ce(IV). The nuclease and anticancer activities of 1 were investigated. The roles of the tert-butyl group and singlet oxygen in the DNA cleavage activity were also discussed.
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