4.7 Article

A Dodecanuclear Dysprosium Wheel Assembled by Six Vertex-Sharing Dy3 Triangles Exhibiting Slow Magnetic Relaxation

Journal

INORGANIC CHEMISTRY
Volume 51, Issue 11, Pages 5994-5996

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic3005807

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Funding

  1. National Natural Science Foundation of China [91022009, 20921002]

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Reactions of lanthanide(III) (Ln(III)) perchlorate (Ln = Dy and Ho) and a polydentate Schiff base resulted in the unprecedented assembly of novel Ln(12) wheels containing six vertex-sharing Ln(3) triangles. The Dy-12 derivative represents the largest lanthanide wheel based on the peculiar Dy-3 triangles showing slow magnetic relaxation.

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