Journal
INORGANIC CHEMISTRY
Volume 51, Issue 10, Pages 5617-5626Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic300531b
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Funding
- German Science Foundation (DFG)
- Fonds der Chemischen Industrie
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The synthesis and full characterization of a new heteroleptic N-heterocyclic carbene (NHC)-phosphine platinum(0) complex and formation of its corresponding alane adduct is reported. The influence of the ligands on the Lewis basic properties was studied via multinuclear NMR-spectroscopy, X-ray analyses, and density functional theory (DFT) calculations. Consistently, the effect of changing the halogens upon the Lewis acid properties of aluminum halides was studied by X-ray analysis and DFT calculations.
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