4.7 Article

In Situ Formed White-Light-Emitting Lanthanide-Zinc-Organic Frameworks

Journal

INORGANIC CHEMISTRY
Volume 51, Issue 3, Pages 1201-1203

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic201425v

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Funding

  1. National Natural Science Foundation of China [20971015]
  2. Fundamental Research Funds for the Central Universities

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Five novel 3D heterometallic lanthanide-zinc-organic frameworks, [H(H2O)(8)]-[LnZn(4)(imdc)(4)(Him)(4)] [Ln = La (1), Pr (2), Eu (3), Gd (4), Tb (5); H(3)imdc = 4,5-imidazoledicarboxylic acid; Him = imidazole], were synthesized via an in situ hydrothermal reaction, and tunable luminescence from yellow to white was obtained through the doping of Eu and Tb ions in the La-Zn framework.

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