Journal
INORGANIC CHEMISTRY
Volume 51, Issue 20, Pages 11150-11154Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic3017479
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Funding
- National Nature Science Foundation of China [21171662]
- SRF for ROCS (State Education Ministry)
- Program for New Century Excellent Talents in University [NECT-11-0958]
- CIAC startup fund
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Two new uranyl arsonates, Zn(UO2)(PhAsO3)(2)L center dot H2O [L = 1,10-phenanthroline (1) and 2,2'-bipyridine (2)], have been synthesized by hydrothermal reactions of phenylarsonic acid, L, and ZnUO2(OAc)(4)center dot 7H(2)O. Single-crystal X-ray analyses demonstrate that these two compounds are isostructural and exhibit one-dimensional chains in which U-VI and Zn-II cations are directly connected by the yl oxygen atoms and additionally bridged by arsonate groups. Both compounds represent the first examples of uranyl arsonates with heterometallic cation-cation interactions.
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