Journal
INORGANIC CHEMISTRY
Volume 51, Issue 19, Pages 10071-10073Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic301228j
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Funding
- National Science Foundation [CHE-1011736]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1011736] Funding Source: National Science Foundation
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Two trifunctional ligands built from enantiopure amino acids and containing a 1,8-naphthalimide group have been used to prepare two new complexes of potassium that have extended structures based on homochiral-rod secondary building units. One structure is a three-dimensional metal-organic framework (MOF), while the other is a two-dimensional solid that is organized into a supramolecular MOF by strong pi center dot center dot center dot pi-stacking interactions of the naphthalimide groups in the third dimension.
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