Journal
INORGANIC CHEMISTRY
Volume 51, Issue 7, Pages 3935-3937Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic3001762
Keywords
-
Categories
Funding
- POSDRU [107/1.5/S/80765]
Ask authors/readers for more resources
A novel dodecanuclear complex, [{(HL)(L)(DMF)(CuGdIII)-Gd-II(DMF)(H2O)}(6)]center dot 6DMF (1; DMF = N,N-dimethylformamide), has been obtained using the ligand resulting from the condensation of 3-formylsalicylic acid with hydroxylamine (H3L). The exchange interaction between the phenoxo-bridged Cu-II and Gd-III ions is weak ferromagnetic (J = +1.01 cm(-1)). The combination of a high-spin ground state with small anisotropy leads to a significant magnetocaloric effect [-Delta S-m(0-7 T) = 23.5 J K g(-1) K-1 at similar to 2 K].
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available