Journal
INORGANIC CHEMISTRY
Volume 50, Issue 18, Pages 9147-9152Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic201376t
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Funding
- BASF SE
- Energy Frontier Research Center
- U.S. Department of Energy (DOE)
- U.S. DOE Office of Basic Energy Sciences [DE-FG02-08ER15935]
- MEST in Korea [2009-0084799]
- WCU, Korea
- National Research Foundation of Korea [2009-0084799] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The concept and occurrence of isoreticular (same topology) series of metal organic frameworks (MOFs) is reviewed. We describe the preparation, characterization, and crystal structures of three new MOFs that are isoreticular expansions of known materials with the tbo (Cu-3(4,4',4 ''-(benzene-1,3,5-triyl-tris(benzene-4,1-diy1))tribenzoate)(2), MO F-399) and pto topologies (Cu-3(4,4',4 ''-(benzene-1,3,5-triyltribenzoate)(2), MOF-143; Cu-3(4,4',4 ''-(triazine-2,4,6-triyl-tris-(benzene-4,1-diyl))tribenzoate)(2), MOF-388). One of these materials (MOF-399) has a unit cell volume 17 times larger than that of the first reported material isoreticular to it, and has the highest porosity (94%) and lowest density (0.126 g cm(-3)) of any MOFs reported to date.
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