Journal
INORGANIC CHEMISTRY
Volume 50, Issue 7, Pages 2870-2877Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic102076g
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Funding
- UCLA
- Department of Energy [ER15984]
- Sloan Foundation
- University of Erlangen-Nuremburg
- DFG
- Bavarian California Technology Center (BaCaTec)
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- MRCAT member institutions
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Two series of Schiff base metal complexes were investigated, where each series was supported by an ancillary ligand incorporating a ferrocene backbone and different N=X functionalities. One ligand is based on an imine, while the other is based on an iminophosphorane group. Cerium(IV), cerium(III), and yttrium(III) alkoxide complexes supported by the two ligands were synthesized. All metal complexes were characterized by cyclic voltammetry. Additionally, NMR, Mossbauer, X-ray absorption near-edge structure (XANES), and absorption spectroscopies were used. The experimental data indicate that iron remains in the +2 oxidation state and that cerium(IV) does not engage in a redox behavior with the ancillary ligand.
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