Journal
INORGANIC CHEMISTRY
Volume 50, Issue 7, Pages 2720-2722Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic1025262
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- Department of Science and Technology, New Delhi, India
- Council of Scientific and Industrial Research, New Delhi, India
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Dinuclear salen compounds of zirconium and hafnium are efficient initiators for the solvent-free ring-opening polymerization of cyclic ester monomers and lactides. There is a correlation between the theoretical and experimental number-average molecular weights (M-n's) in these polymerizations. Polymerization of beta-butyrolactone gives poly(3-hydroxybutyrate) with a good M-n and molecular weight distribution.
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