Journal
INORGANIC CHEMISTRY
Volume 50, Issue 23, Pages 11865-11867Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic2021963
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Funding
- GNR MATINEX of PACEN program
- French ANR [ANR-08-BLAN-0216-01]
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An uranium trimesate open framework is built up from trinuclear building blocks (mu(3)-OU(3)) connected to each other by tricarboxylate linkers to generate honeycomb-like 3D topology. This compound was solvothermally synthesized from low-valent uranium in an N,N-dimethylformamide solvent under an inert atmosphere, favoring stabilization of the tetravalent oxidation state, which is confirmed by X-ray photoelectron spectroscopy analysis.
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