Journal
INORGANIC CHEMISTRY
Volume 50, Issue 3, Pages 729-731Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic102436b
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Funding
- U.C.S.D.
- NSF [CHE-0952370, CHE-9709183, CHE-0116662, CHE-0741968]
- Department of Energy [DE-FG02-08ER46519]
- NCI [3R01 CA095298-07S1]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0952370] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0741968] Funding Source: National Science Foundation
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A microwave-assisted postsynthetic modification (PSM) reaction on a metal-organic framework (MOF) has been realized. Cyanation of the Zr4+-based UiO-66-Br was achieved with CuCN and microwave irradiation to produce UiO-66-CN. This protocol represents a notable example of PSM on an aryl halide MOF producing a cyano-functionalized MOF.
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