Journal
INORGANIC CHEMISTRY
Volume 50, Issue 11, Pages 4671-4673Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic2001688
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- University of California at Riverside
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Endohedrally functionalized bis(pyridine) ligands show the ability to self-discriminate when treated with coordinating metals to form self-assembled clusters. Self-sorting between components is controlled by substitution on the interior of the complex. Tuning the size of the internal substituent allows selective heterocluster formation, determined by noncovalent and space-filling interactions. This novel method of self-sorting allows discrimination between ligands of identical geometry and donor type.
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