Journal
INORGANIC CHEMISTRY
Volume 50, Issue 21, Pages 10534-10536Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic2017598
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Funding
- Department of Energy [DE-FG02-08ER46519]
- China Scholarship Council
- U.S. Department of Energy (DOE) [DE-FG02-08ER46519] Funding Source: U.S. Department of Energy (DOE)
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A postsynthetic modification (PSM) scheme for metal-organic frameworks (MOFs) has been developed using a tetrazine-based Click reaction. It was found that the efficacy of this modification procedure was dependent on the MOF topology and, in the case of an isoreticular MOF (IRMOF) system, required the formation of a mixed-ligand IRMOF with a suitable ratio of 1,4-benzenedicarboxylate (BDC) and an olefin-tagged BDC derivative. On the basis of the versatile use of tetrazine Click chemistry in bioconjugate chemistry, we expect that this scheme will prove to be a useful reaction for preparing functionalized materials, including MOFs.
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