Journal
INORGANIC CHEMISTRY
Volume 50, Issue 10, Pages 4247-4249Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic200533e
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- Alexander von Humboldt Foundation
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Electrophilic quenching of a carbene-stabilized pi-boryl anion with the Bronsted acid Et3NHCl provides a convenient synthetic route to the parent NHC-stabilized 1-hydroborole, which isomerizes to the corresponding 3-hydroborole via two successive nondegenerate [1,5]-sigmatropic hydrogen migrations. Molecular structures of both isomers have been determined by X-ray crystallography.
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