4.7 Article

Nuclearity Control of a Trisaloph Zinc Cluster Complex Dependent on Minute Structural Differences in the Bridging Anions

Journal

INORGANIC CHEMISTRY
Volume 50, Issue 12, Pages 5315-5317

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic2002833

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Funding

  1. MEXT of Japan
  2. Grants-in-Aid for Scientific Research [22108505, 23750055] Funding Source: KAKEN

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The Zn(6) cluster complex 2 of the trisaloph ligand was synthesized using EtCO(2)(-) anions as bridging ligands. Complex 2 has a dimeric structure in the crystalline state, while two monomeric isomers were in equilibrium in solution. The anion-exchange reaction successfully resulted in nuclearity control from Zn(7) to Zn(6).

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