Borane-Mediated Silylation of a Metal-Oxo Ligand

The addition of 1 equiv of HSiPh(3) to UO(2)-((Ar)acnac)(2) ((Ar)acnac = ArNC(Ph)CHC(Ph)O; Ar = 3, 5-(t)Bu(2)C(6)H(3)), in the presence of 1 equiv of B(C(6)F(5))(3), results in the formation of U(OSiPh(3))(OB{C(6)F(5)}(3))((Ar)acnac)(2) (1), via silylation of an oxo ligand and reduction of the uranium center. The addition of 1 equiv of Cp(2)Co to 1 results in a reduction to uranium(IV) and the formation of [Cp(2)Co]-[U(OSiPh(3))(OB{C(6)F(s)}(3))((Ar)acnac)(2)] (2) in 78% yield. Complexes 1 and 2 have been characterized by X-ray crystallography, while the solution-phase redox properties of 1 have been measured with cyclic voltammetry.