Journal
INORGANIC CHEMISTRY
Volume 50, Issue 22, Pages 11288-11290Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic201697g
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Funding
- National Science Foundation [CHE09-11110, CHE04-43580, CHE08-40523, CHE09-46690]
- Sandia National Laboratories [14938, 151300]
- Natural Sciences and Engineering Research Council of Canada
- United States Department of Energy [DE-AC04-94AL85000]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0840523] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0946690] Funding Source: National Science Foundation
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The P,P-chelated stannylene [(i-Pr2P)(2)N](2)Sn takes up 2 equiv of carbon dioxide (CO2) to form an unusual product in which CO2 binds to the Sn and P atoms, thus forming a six-membered ring complex. Gentle heating of the solid product releases CO2, indicating that CO2 is bound as an adduct to the main-group complex. The groups bound to the CO2 fragment are not particularly sterically crowded or highly acidic, thus indicating that frustrated Lewis acid-base pairs are not required in the binding of CO2 to main-group elements.
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