Journal
INORGANIC CHEMISTRY
Volume 51, Issue 1, Pages 298-311Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic201663m
Keywords
-
Categories
Funding
- Department of Science and Technology (DST), New Delhi, India [SR/S1/IC-15/2006]
- Council of Scientific and Industrial Research (CSIR), New Delhi, India [9/13(288)/2010-EMR-I]
Ask authors/readers for more resources
The synthesis and characterization of ferrocene (Fc) derivatives 4[2,5-diferrocenyl-4-(4-pyridyl)imidazolidin-1-yl-methyl]pyridine (1), ferrocenylmethylenepyridin-3-ylmethylamine (2), N,N'-bis(ferrocenylmethylene)-2,4,6-trimethylbenzene-1,3-diamine (3), and 6-ferrocenyl-5,6-dihydro[4,5]imidazo[1,2-c]quinazoline (4) have been described. Structures of 1, 2, and 4 have been determined by single-crystal X-ray diffraction analyses. At 25 degrees C, 1-3 are nonfluorescent, while 4 displays moderate fluorescence and chromogenic, fluorogenic, and electrochemical sensing selectively toward Hg2+ and Pb2+ ions. Association constants (K-a) for Hg2+ and Pb2+ have been determined by the Benesi-Hildebrand method. Job's plot analysis supported 1:1 and 1:2 stoichiometries for Hg2+ and Pb2+ ions. Cyclic voltammograms of 1-4 exhibited reversible waves corresponding to a ferrocene/ferrocenium couple. The wave associated with 4 (+0.0263 V) exhibited positive (Delta E-pa = 0.136 V) and negative (Delta E-pa = 0.025 V) shifts in the presence of Hg2+ and Pb2+ ions, respectively. The mode of interaction between metal ions and 4 has been supported by H-1 NMR spectroscopy and mass spectrometry studies and verified by theoretical studies. It presents the first report dealing with ferrocene-substituted quinazoline as a multichannel chemosensor for Hg2+/Pb2+ ions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available