4.7 Article

A High-Nuclearity 3d/4f Metal Oxime Cluster: An Unusual Ni8Dy8 Core-Shell Complex from the Use of 2-Pyridinealdoxime

Journal

INORGANIC CHEMISTRY
Volume 49, Issue 21, Pages 9743-9745

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic101581g

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Funding

  1. NSF [CHE-0910472]
  2. Division Of Chemistry
  3. Direct For Mathematical & Physical Scien [910472] Funding Source: National Science Foundation

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The initial employment of 2-pyridinealdoxime in 3d/4f chemistry has led to a (Ni8Dy8III)-Dy-II cluster with an unprecedented metal topology; the compound has an unusual structure, is the highest-nuclearity metal oxime cluster to date, and exhibits slow magnetization relaxation.

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