4.7 Article

An Undecanuclear Fe-III Single-Molecule Magnet

Journal

INORGANIC CHEMISTRY
Volume 49, Issue 1, Pages 1-3

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic901747w

Keywords

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Funding

  1. DFG [CIFN, SPP 1137]
  2. MAG-MANet [NMP3-CT-2005-515767]
  3. Conseil Regional d'Aquitaine
  4. GIS Advanced Materials in Aquitaine (COMET Project)
  5. Universite de Bordeaux
  6. CNRS

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The undecanuclear complex in [Fe-11(III)(mu(4)-O)(3)(mu(3)-O)(4)(L)(3)(mu-O2CCMe3)(12)]Cl center dot 5MeCN has been synthesized and characterized by single-crystal X-ray crystallography. Mossbauer spectroscopy and bulk susceptibility studies reveal that the complex has an S = 13/2 spin ground state and exhibits single-molecule-magnet behavior.

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