Journal
INORGANIC CHEMISTRY
Volume 49, Issue 16, Pages 7220-7222Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic100725j
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Funding
- NMR at Nara Institute of Science and Technology
- Young Scientists [21791957]
- Grants-in-Aid for Scientific Research [21791957] Funding Source: KAKEN
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A zinc(II)-included hemicryptophane, which has a zinc(II) center embedded in the cavity, was synthesized and characterized. The catalytic activity of the hemicryptophane was tested in the hydrolysis of methyl para-nitrophenyl carbonate (MPC). A direct comparison between the hemicryptophane and the model complex, which lacks a cavity, demonstrated that the cage structure enhanced the catalytic activity.
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