Journal
INORGANIC CHEMISTRY
Volume 49, Issue 17, Pages 7620-7622Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic101136j
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Funding
- Purdue University
- National Science Foundation [CHE-0541587, CHE-0910552]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0910552] Funding Source: National Science Foundation
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The uranium(IV) terminal oxo species Tp(2)(star)U(O) has been synthesized by oxygen-atom transfer from pyridine-N-oxide to Tp(2)(star)U(2,2'-bipyridine), a trivalent uranium species with a monoanionic bipyridine ligand. Full characterization of the oxo species using H-1 NMR and IR spectroscopies, X-ray crystallography, and computational studies was performed.
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