Journal
INORGANIC CHEMISTRY
Volume 49, Issue 18, Pages 8444-8448Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic1010083
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Funding
- NSF [CHE 0718281]
- Welch Foundation [AX-1730]
- National Science Foundation/Department of Energy [NSF/CHE-0822838]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0822838] Funding Source: National Science Foundation
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A three-dimensional microporous metal organic framework, Zn-5(BTA)(6)(TDA)(2)center dot 15DMF center dot 8H(2)O (1; HBTA = 1,2,3-benzenetriazole; H(2)TDA = thiophene-2,5-dicarboxylic acid), comprising pentanuclear [Zn-5]cluster units, was obtained through an one-pot solvothermal reaction of Zn(NO3)(2), 1,2,3-benzenetriazole, and thiophene-2,5-dicarboxylate. The activated 1 displays typed-I N-2 gas sorption behavior with a Langmuir surface area of 607 m(2) g(-1) and exhibits interesting selective gas adsorption for C2H2/CH4 and CO2/CH4.
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