Journal
INORGANIC CHEMISTRY
Volume 49, Issue 17, Pages 8067-8072Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic1011605
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Funding
- DFG
- MAGMANet [NMP3-CT-2005-515767]
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A series of five isostructural tetranuclear lanthanide complexes of formula [Ln(4)(mu(3)-OH)(2)(mdeaH)(2)(piv)(8)], (mdeaH(2) = N-methyldiethanolamine; piv = pivalate; Ln = Tb (1), Dy (2), Ho (3), Er (4), and Tm (5)) have been synthesized and characterized. These clusters have a planar butterfly Ln(4) core. Magnetically, the Ln(III) ions are weakly coupled in all cases; the Dy-4 compound 2 shows Single Molecule Magnet (SMM) behavior.
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