Journal
INORGANIC CHEMISTRY
Volume 49, Issue 3, Pages 775-777Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic9023162
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- Deutsche Forschungsgemeinschaft
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The first structurally described cobalt(l) Lewis-base-stabilized silylene complex [Co(CO)(3){SiCl2(IPr)}(2)](+)[CoCl3(THF)](-) [1; IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene] was prepared by applying the two-electron sigma-donor ligand SiCl2(IPr) through coordination with Co-2(CO)(8). The bonding situation between ligand SiCl2-(IPr) and the cobalt(I) metal center in [Co(CO)(3){SiCl2(IPr)}(2)](+) of 1 was investigated by H-1 NMR and IR spectroscopy, single-crystal X-ray structural analysis, and density functional theoretical calculations.
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