4.7 Article

Catalytic Water Oxidation by Single-Site Ruthenium Catalysts

Journal

INORGANIC CHEMISTRY
Volume 49, Issue 4, Pages 1277-1279

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic901437e

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Funding

  1. U.S. Department of Energy [DE-FG02-06ER15788, DE-SC0001011]
  2. UNC EFRC
  3. U.S. Department of Energy (DOE) [DE-FG02-06ER15788, DE-SC0001011] Funding Source: U.S. Department of Energy (DOE)

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A series of monomeric ruthenium polypyridyl complexes have been synthesized and characterized, and their performance as water oxidation catalysts has been evaluated. The diversity of ligand environments and how they influence rates and reaction thermodynamics create a platform for catalyst design with controllable reactivity based on ligand variations.

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