4.7 Article

Rare Oxidation-State Combinations and Unusual Structural Motifs in Hexanuclear Mn Complexes Using 2-Pyridyloximate Ligands

Journal

INORGANIC CHEMISTRY
Volume 49, Issue 10, Pages 4388-4390

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic100089y

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Funding

  1. Cyprus Research Promotion Foundation [TECHNO/0506/06]
  2. Office of Science, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-AC02-05CH11231]

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The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented ((Mn4MnMnIV)-Mn-II-Mn-III) or extremely rare ((MnMn5III)-Mn-II and (Mn3Mn3III)-Mn-II) metal oxidation-state combinations and uncommon structural motifs.

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