Journal
INORGANIC CHEMISTRY
Volume 49, Issue 15, Pages 6784-6786Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic1008285
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- Spanish MCI [CTQ2009-06959, MAT2009-13977-C03]
- CONSOLIDER-INGENIO in Molecular Nanoscience [CSD2007-00010]
- U.S. Department of Energy [DE-AC02-05CH11231]
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A new ligand has been synthesized with the aim of favoring distinct coordination environments within lanthanide polynuclear complexes. It has led to the formation of three unsymmetrical [Ln(2)(III)] (Ln=Gd, Tb, Eu) complexes, exhibiting weak antiferromagnetic coupling and, for Eu and Tb, high single-ion magnetic anisotropy. All of these attributes are necessary for these clusters to behave as possible 2qubit quantum gates.
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