Journal
INORGANIC CHEMISTRY
Volume 49, Issue 20, Pages 9617-9626Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic101278w
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Funding
- National Natural Science Fund of China [20801049, 20771095]
- Natural Scientific Research of Zhengzhou University of Light Industry [2007BSJJ001]
- Henan Outstanding Youth Science Fund
- Tianjin Normal University
- Spanish Government [CTQ2009-06959]
- Spanish Government (Ramon y Cajal)
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Two Cu-II coordination complexes {[Cu(ces)(H2O)(2)](H2O)(0.5)}(n) (1) and [Cu-15(dhs)(6)(OH)(6)(H2O)(10)](H2O)(20) (2) have been synthesized from cis-epoxysuccinic acid (cis-H(2)ces) and Cu-II perchlorate under different pH conditions (ces = cis-epoxysuccinate and dhs = 2,3-dihydroxysuccinate), and fully characterized by IR spectra, elemental analyses, as well as single crystal and powder X-ray diffraction techniques. Notably, when the reaction was performed at pH above about 7.4, a one-dimensional (1-D) helical chain complex 1 is formed, whereas a neutral isolated Cu-15 nanocluster 2 is generated when the pH value is decreased to the range of about 6.6-7.3, being concomitant with in situ S(N)2 ringcleavage reaction of cis-H(2)ces to form (2S,3S)- and (2R,3R)-H(4)dhs. Further, extended supramolecular architectures are constructed via secondary interactions in both structures. The magnetic properties of 1 and 2 have also been studied in detail, showing that 1 is an antiferromagnetic helical chain of S= 1/2 spins and 2 possesses an S=3/2 spin ground state.
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