Journal
INORGANIC CHEMISTRY
Volume 49, Issue 22, Pages 10687-10693Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic1015127
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- Minnesota State University, Mankato, Minnesota, U.S.A
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Polycrystalline hydroxyapatites Ca10-xREEx(PO4)(6)(OH)(2-x)O-x were synthesized and studied by X-ray powder diffraction, infrared absorption, diffuse-reflectance spectroscopy, and thermogravimetry. The solubility limits x(max) Of rare earth elements (REE) in Ca hydroxyapatites decreases with an increasing REE atomic number from x(max) = 2.00 for La, Pr, and Nd to x(max) = 0.20 for Yb at 1100 degrees C. Refinements of X-ray diffraction patterns by the Rietveld method show that REE atoms substitute for Ca preferentially at the Ca(2) sites of the apatite structure. The substitution decreases the Ca(2)-O(4) atomic distances in the calcium coordination polyhedra and increases the Ca(2)-O(1,2,3) distances. This observation shows that interatomic distances depend not only on radii of the ions involved in the substitution but also on their charges.
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