Journal
INORGANIC CHEMISTRY
Volume 49, Issue 17, Pages 7605-7607Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic100822s
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Funding
- National Natural Science Foundation of China [90922014, 20701025]
- Natural Science Foundation of Shandong Province [Y2008B01]
- Shandong University
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Two isostructural lanthanide organic frameworks (1 and 2) with 2-fold interpenetrating nets have been synthesized based on 1,4-benzenedicarboxylic acid (H2BDC). By application of an organic ligand with hindrance groups and a terminal chelating ligand to replace BDC and coordinated solvates, interpenetration has been effectively controlled. The gas-sorption properties of the noninterpenetrating net have been studied.
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