Journal
INORGANIC CHEMISTRY
Volume 49, Issue 15, Pages 6974-6985Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic1006082
Keywords
-
Categories
Funding
- Principado de Asturias [IB05-069, IB08-104]
- Ministeno de Ciencia y Tecnologia [CTQ2006-07036/BQU, CTQ-2006-08924]
- Junta de Castilla y Leon [VA017B08, VA070A08]
- Ministeno de Educacion y Ciencia for a Raman y Cajal contract
Ask authors/readers for more resources
New molybdenum(0), molybdenum(II), manganese(I), rhenium(I), silver(I), and copper(I) complexes with the 1,3,5-tris(thiocyanatomethyl)mesitylene [Ms(CH2SCN)(3)] ligand have been synthesized and characterized by IR, NMR, and by X-ray diffraction (except for the rhenium complex). The Ms(CH2SCN)(3) ligand coordinated with the molybdenum, manganese, and rhenium carbonyl fragments as a tripodal chelate. With copper and silver, dimeric dicationic species were obtained instead, with the Ms(CH2SCN)(3) ligand acting simultaneously as a bidentate chelate and bridge. The [{Cu(Ms(CH2SCN)(3))}(2)][BAr'(4)](2) (BAr'(4) = tetra(3,5-bis(trifluoromethyl)phenyl)borate) product is an excellent catalyst for cyclopropanation and aziridination of alkenes and cyclopropenation of alkynes by means of carbene- and nitrene-transfer reactions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available