Journal
INORGANIC CHEMISTRY
Volume 49, Issue 9, Pages 3977-3979Publisher
AMER CHEMICAL SOC
DOI: 10.1021/IC100390x
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- Israel Science Foundation
- United States-Israel Binational Science Foundation
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Dithiodiolate ligands were synthesized by reacting 1,2-ethanedithiol or 1,2-benzenedithiol with 2,2-bis(trifluoromethyl)oxirane, led selectively to mononuclear octahedral group 4 complexes of the type [{OSSO}M(OR)(2)], which features C-2 symmetry and fluxional behavior, and were highly active in the ring-opening polymerization of rac- and L-lactide.
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