Journal
INORGANIC CHEMISTRY
Volume 49, Issue 4, Pages 1286-1288Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic902136f
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Funding
- Major State Basic Research Development Program [2006CB806104, 2007CB925100]
- NSFC [20531040, 20721002]
- enterprise academician workstation in Changzhou Trina Solar Energy Co. Ltd., Jiangsu Province
- China Post-doctoral Science Foundation [20090451189]
- Nanjing University
- Department of Education of Jiangxi Province [GJJ10536]
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Two novel homochiral enantiomers, trinuclear ionic clusters [(NiL(1))(2)-Na](+)NCS(-) center dot MeOH center dot Et(2)O (1) and [(NiL(2))(2)Na](+)NCS(-) center dot MeOH center dot Et(2)O (2) [H(2)L(1) = N,N-bis(3-methoxysalicylidene)-(1R,2R)-1,2-diphenylenediamine; H(2)L(2) = N,N-bis(3-methoxysalicylidene)-(1S,2S)-1,2-diphenylenediamine], have been synthesized and structurally characterized. Both complexes have C(2) symmetry and crystallize in space group P2(1). Ferroelectric measurements reveal that complexes 1 and 2 represent a new type of ionic ferroelectric based on metal-organic coordination with a polarization value higher than that of KH(2)PO(4).
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