4.7 Article

Novel Functionalized Metal-Organic Framework Based on Unique Hexagonal Prismatic Clusters

Journal

INORGANIC CHEMISTRY
Volume 49, Issue 19, Pages 8647-8649

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic100558x

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Funding

  1. NSFC [20771038]
  2. Shanghai Leading Academic Discipline Project [B409]

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The novel porous 3D metal-organic framework synthesized from fluorenone-2,7-dicarboxylate contains zinc-glycolate carboxylate layers in which the unique hexagonal prismatic [Zn-6(OCH2CH2O)(6)] clusters are connected by planar [Zn-3(OCH2CH2O)(COO)(2)] motifs; the pore surface is furnished with carbonyl groups and open metal sites.

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