Journal
INORGANIC CHEMISTRY
Volume 49, Issue 11, Pages 4753-4755Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic1006605
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Funding
- NSF [CHE-0914935, CHE-023488]
- University of Missouri-St. Louis
- Virginia Tech
- University of Bordeaux
- ANR [NT09_469563]
- Region Aquitaine
- GIS Advanced Materials in Aquitaine
- MAGMANet [NMP3-CT-2005-515767]
- CNRS [4659]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0914935] Funding Source: National Science Foundation
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Treatment of tris(3-cyano-2,4-pentanedionato)manganese(III) with KTp*, followed by [NEt4]CN affords [NEt4][(Tp*)Mn-III(CN)(3)] (1); subsequent treatment of 1 with divalent triflates (OTf) and 2,2'-bipyridine (bpy) affords {(Mn2M2II)-M-III} complexes (M-II = Mn, 2; Ni, 3). Magnetic measurements show that 1-3 exhibit S-T = 1, 3, and 4 spin ground states, respectively.
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