4.7 Article

First Structurally Characterized Tricyanomanganate(III) and its Magnetic {MnIII2MII2} Complexes (MII = Mn, Ni)

Journal

INORGANIC CHEMISTRY
Volume 49, Issue 11, Pages 4753-4755

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic1006605

Keywords

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Funding

  1. NSF [CHE-0914935, CHE-023488]
  2. University of Missouri-St. Louis
  3. Virginia Tech
  4. University of Bordeaux
  5. ANR [NT09_469563]
  6. Region Aquitaine
  7. GIS Advanced Materials in Aquitaine
  8. MAGMANet [NMP3-CT-2005-515767]
  9. CNRS [4659]
  10. Direct For Mathematical & Physical Scien
  11. Division Of Chemistry [0914935] Funding Source: National Science Foundation

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Treatment of tris(3-cyano-2,4-pentanedionato)manganese(III) with KTp*, followed by [NEt4]CN affords [NEt4][(Tp*)Mn-III(CN)(3)] (1); subsequent treatment of 1 with divalent triflates (OTf) and 2,2'-bipyridine (bpy) affords {(Mn2M2II)-M-III} complexes (M-II = Mn, 2; Ni, 3). Magnetic measurements show that 1-3 exhibit S-T = 1, 3, and 4 spin ground states, respectively.

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