Journal
INORGANIC CHEMISTRY
Volume 49, Issue 11, Pages 4741-4743Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic1004352
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- U.S. Department of Energy, Office of Basic Energy Sciences [DE-FG02-06ER15794]
- U.S. Department of Energy (DOE) [DE-FG02-06ER15794] Funding Source: U.S. Department of Energy (DOE)
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Low catalyst loading of a cationic oxorhenium(V) oxazoline complex, [2-(2'-hydroxyphenyl)-2-oxazolinato(-2)]oxorhenium(v), condenses diols and aldehydes to give 1,3-dioxolanes in excellent yields under neat conditions and reasonably mild temperatures. The reaction is applicable to biomass-derived furfural and glycerol. The resulting cyclic acetals may find use as value-added chemicals and/or oxygenate fuel additives. Differences in the stereoselectivity of the reaction for epoxides versus diols provide insight into the reaction mechanism.
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