Journal
INORGANIC CHEMISTRY
Volume 48, Issue 8, Pages 3342-3359Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic801027q
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Funding
- CEEX Program [D11-17]
- EC [NMP3-CT-2005515767]
- National Science Fund [20221101, 20490210]
- National Basic Research Program of China [2006CB601102]
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Heterometallic 3d-4f complexes are of high interest in molecular magnetism: the lanthanide ions bring large and, in most cases, anisotropic magnetic moments. The combination of 3d and 4f metal ions, which differ through their chemistries and stereochemical preferences, leads to a rich variety of heterometal complexes, ranging from discrete entities to 3-D coordination polymers. This paper reviews recent achievements in this field: (i) oligonuclear complexes for studying the nature of the 3d-4f exchange interaction; (ii) construction of single-molecule magnets; (iii) magnetic properties of 3d-4f coordination polymers.
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