Journal
INORGANIC CHEMISTRY
Volume 48, Issue 9, Pages 3943-3953Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic801453w
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Funding
- CEA/DEN/DSOE/RB
- Paris GNR
- ACTINET Network
- French Toxicology Nuclear Program
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Nitrilotriacetic acid, commonly known as NITA (N(CH2CO2H)(3)), can be considered a representative of the polyaminocarboxylic family. The results presented in this paper describe the thermodynamical complexation and structural investigation of An(IV) complexes with NTA in aqueous solution. In the first part, the stability constants of the An(IV) complexes (An = Pu, Np, U, and Th) have been determined by spectrophotometry. In the second part, the coordination spheres of the actinide cation in these complexes have been described using extended X-ray absorption fine structure spectroscopy and compared to the solid-state structure of (Hpy)(2)[U(NTA)(2)] center dot (H2O). These data are further compared to quantum chemical calculations, and their evolution across the actinide series is discussed. In particular, an interpretation of the role of the nitrogen atom in the coordination mode is proposed. These results are considered to be model behavior of polyaminocarboxylic ligands such as diethylenetriamine pentaacetic acid, which is nowadays the best candidate for a chelating agent in the framework of actinide decorporation for the human body.
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