4.7 Article

Magnesium-Based 3D Metal-Organic Framework Exhibiting Hydrogen-Sorption Hysteresis

Journal

INORGANIC CHEMISTRY
Volume 48, Issue 17, Pages 8069-8071

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic901056d

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Funding

  1. National Natural Science Foundation of China [20631040, 20771099]
  2. MOST of China [2006CB601103, 2006DFA42610]

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A new magnesium metal-organic framework (MOF) based on an asymmetrical ligand, biphenyl-3,4',5-tricarboxylate (H3PT) has been synthesized and structurally characterized. MOF Mg-3(BPT)(2)(H2O)(4) (1) consists of 10 hexagonal nanotube-like channels and exhibits pronounced hydrogen-sorption hysteresis at medium pressure.

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