4.7 Article

A Chiral Luminescent Coordination Polymer Featuring a Unique 4-Connected Self-Catenated Topology Built from Helical Motifs

Journal

INORGANIC CHEMISTRY
Volume 48, Issue 7, Pages 2723-2725

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic900241q

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Funding

  1. American Chemical Society Petroleum Research Fund

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The luminescent chiral coordination polymer {[Cd(pht)(dpa)(H2O)(H2O)] center dot 4H(2)O}(n) (pht = phthalate; dpa = 4,4'-dipyridylamine) possesses an unprecedented 4-connected uninodal self-catenated three-dimensional 7(4)8(2) network topology, constructed from the interlocking of [Cd(dpa)](n) double helices with [Cd(pht)](n) single helices.

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