Journal
INORGANIC CHEMISTRY
Volume 48, Issue 4, Pages 1722-1730Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic801883e
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Funding
- Natural Sciencess and Engineering Research Council (NSERC) of Canada
- Canada Foundation
- Ontario Ministry of Research and Innovation Early Researcher Award (OMRI-ERA)
- University of Western Ontario
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A series of coordination complexes, where a heavy chalcogen (Se, Te) acts as the acceptor site, using a variety of electron rich Lewis bases (phosphine, imine, N-heterocyclic carbene), have been synthesized and comprehensively characterized. Each derivative is a representative example of a E -> Ch coordinative bond, characterizing an efficient E-E bond forming methodology and a systematic investigation into the coordination chemistry of the chalcogens. The complexes are susceptible to classic ligand exchange reactions, verifying the dative E -> Ch bonding motif.
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