4.7 Article

A Three-Dimensional Porous Metal-Organic Framework Constructed from Two-Dimensional Sheets via Interdigitation Exhibiting Dynamic Features

Journal

INORGANIC CHEMISTRY
Volume 48, Issue 11, Pages 4616-4618

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic900372t

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Funding

  1. U.S. Department of Energy [DE-AC02-06CH11357]
  2. National Science Foundation [CHE-0449634, DMR-800415, CHE-0535644]
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [0822838, 0910761] Funding Source: National Science Foundation

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A three-dimensional porous metal-organic framework (PCN-18) was constructed through interdigitating two-dimensional grid sheets composed of 4,4'-(anthracene-9,10-diyl)dibenzoate and copper paddlewheel secondary building units, and its dynamic features were evidenced by gas sorption isotherms.

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