Journal
INORGANIC CHEMISTRY
Volume 48, Issue 8, Pages 3517-3519Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic900306t
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Funding
- NSF of China [20801037]
- A. v. Humboldt Foundation
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A new layered zinc phosphite, H(2)tmdp center dot Zn-3(HPO3)(4) (tmdp = 4,4'-trimethylenedipiperidine), was prepared in a flux of phosphorous acid without the addition of water as a solvent. The compound could be transformed into a new three-dimensional open-framework zinc phosphite, Zn-2(H2O)(4)(HPO3)(2). H2O, with intersecting 16- and 12-ring channels at room temperature.
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